Abstract
Rate constants for the deprotonation reaction of N-phenacyl-4- R-pyridinium bromides (R=H, CH 3, CN) with 1,4-diazabicyclo[2.2.2]octane were measured in three silicon polypodands, Me 2Si24, EtSi34 and PhSi34. Silicon polypodands as open molecular capsules lower the deprotonation rates but increase the stability of the formed ylides in comparison to DMSO and water.
Full Text 
Sign-in/Register to access full text options
Sign-in/Register to access full text options 
Published version (
Free)
Free) 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a call
