General Strategy to Fabricate Porous Co-Based Bimetallic Metal Oxide Nanosheets for High-Performance CO Sensing.

Abstract

Two-dimensional (2D) porous bimetallic oxide nanosheets are attractive for high-performance gas sensing because of their porous structures, high surface areas, and cooperative effects. Nevertheless, it is still a huge challenge to synthesize these nanomaterials. Herein, we report a general strategy to fabricate porous cobalt-based bimetallic oxide nanosheets (Co-M-O NSs, M = Cu, Mn, Ni, and Zn) with an adjustable Co/M ratio and the homogeneous composition using metal-organic framework (MOF) nanosheets as precursors. The obtained Co-M-O NS possesses the porous nanosheet structure and ultrahigh specific surface areas (146.4-220.7 m2 g-1), which enhance the adsorption of CO molecules, support the transport of electrons, and expose abundant active sites for CO-sensing reaction. As a result, the Co-M-O NS exhibited excellent sensing performances including high response, low working temperature, fast response-recovery, good selectivity and stability, and ppb-level detection limitation toward CO. In particular, the Co-Mn-O NS showed the highest response of 264% to 100 ppm CO at low temperature (175 °C). We propose that the excellent sensing performance is ascribed to the specific porous nanosheet structure, the relatively highly active Co3+ ratio resulting from cation substitution, and large amounts of chemisorbed oxygen species on the surface. Such a general strategy can also be introduced to design noble-metal-free bimetallic metal oxide nanosheets for gas sensing, catalysis, and other energy-related fields.