Abstract
The dynamics of geminate ion-electron recombination following laser photoionization of N,N,N',N'-tetramethyl- p-phenylenediamine (TMPD) in non-polar solution were observed by time resolving the resulting delayed fluorescence. Geminate recombination was observed for TMPD excited by intense (3μJ) picosecond pulses of 305 nm light in low electron mobility solvents. Preliminary comparisons were made to theoretical models.
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