Gelatin/Cellulose Nanofiber-Based Functional Nanocomposite Film Incorporated with Zinc Oxide Nanoparticles

Abstract

A novel bio-based nanocomposite film was developed using the combination of gelatine and cellulose nanofiber (CNF) as a polymer matrix and zinc oxide nanoparticles (ZnONP) as nanofillers. The nanocomposite film solution was developed using simple solution mixing and film prepared by the following casting methods. The fabricated nanocomposite film containing 2 wt% of ZnONP shows excellent UV-light barrier properties (>95%) and high transparency (>75%). The presence of ZnONP also improves the mechanical strength of the film by ~30% compared to pristine gelatin/CNF-based film, while the flexibility and rigidity of the nanocomposite film were also slightly improved. The addition of ZnONP slightly increased (~10%) the hydrophobicity while the water vapor barrier properties remain unaltered. The hydrodynamic properties of the bio-based film were also changed in the presence of ZnONP, moisture content and the swelling ratio slightly enhanced, whereas water solubility was decreased. Moreover, the integration of ZnONP introduced antibacterial activity toward foodborne pathogens. The fabricated bio-based nanocomposite film could be useful in active packaging applications.