Abstract
Vibrational band intensities are obtained from discrete variable representation calculations of eigenstates for H + 3. Transitions linking highly excited states to the ground state show large variations in intensities, with gateway states corresponding to highly excited bending motion (“horseshoes”) which leak intensity into the nearby bath states. It is suggested that these gateway states may be observable. Implications of these results for the interpretation of the infrared predissociation spectra of H + 3 are discussed.
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