Gaseous elemental mercury and its evasion fluxes in the marine boundary layer of the marginal seas of the northwestern Pacific: Results from two cruises in September–December 2019

Abstract

There are many questions regarding the behavior of mercury in the sea-atmosphere system of the northwestern Pacific. Continuous underway measurements of atmospheric gaseous elemental mercury (GEM) and measurements of sea-air GEM evasion fluxes were carried out in the marginal seas of northwestern Pacific from the South China Sea to the Sea of Okhotsk in fall-winter 2019. The median GEM concentration (1.1 ng/m3) was lower than both the background value and the averages previously observed in these areas. A latitudinal gradient of atmospheric GEM and GEM evasion fluxes with maximum values at southern latitudes was found. The following areas have been identified as potential source areas: the Kurill area of the Pacific Ocean Northeast China, Korean Peninsula, and the territory from the southwest coast of the Yellow Sea to the south of Indochina. Seasonal variations were observed in the Sea of Japan and East China Sea with higher GEM concentrations in winter than in fall. Our data and analysis of published data showed significant relationships between GEM evasion fluxes, latitude and sea surface temperature (SST). It seems that on a global scale, along with the GEM gradient between water and atmosphere, SST is the most significant parameter for sea-air GEM evasion fluxes.