Abstract
Some aspects related to the isotherm for the adsorption of a gas on the surface of a solid are reviewed. Two main aspects should be pointed out: 1) a conceptual analysis of the shape of the adsorption isotherm shows that it is a direct source of information on the system being studied (at the same time, some analogies with isotherms belonging to other physicochemical systems are suggested); and 2) a critical review of the large number of theoretical models of the isotherm found in the literature is made, stressing an order based on the principle of maximum likelihood.
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