Abstract

Anodic alumina membranes with an ordered microstructure have been synthesized and investigated. It was found that Knudsen diffusion is the predominant mechanism for gas penetration through the obtained membranes. The technology made it possible to obtain porous membranes with specified structural characteristics for the separation of gas mixtures. Designs of a diffusion element and a gas separation module based on membranes made of anodic aluminum oxide have been developed, and the features of mass transfer under various operating conditions have been studied. The membrane module without recirculation made it possible to concentrate the heavy component from the model helium-methane mixture (99 % / 1 %) up to 18 %. The membrane module with recirculation made it possible to concentrate a light component from a model helium-methane mixture (1 % / 99 %) up to 40 %.

Highlights

  • Anodic alumina membranes with an ordered microstructure have been synthesized and investigated

  • It was found that Knudsen diffusion is the predominant mechanism for gas penetration through the obtained membranes

  • Designs of a diffusion element and a gas separation module based on membranes made of anodic aluminum oxide have been developed, and the features of mass transfer under various operating conditions have been studied

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Summary

Introduction

Anodic alumina membranes with an ordered microstructure have been synthesized and investigated. The membrane module without recirculation made it possible to concentrate the heavy component from the model helium-methane mixture (99 % / 1 %) up to 18 %. The membrane module with recirculation made it possible to concentrate a light component from a model helium-methane mixture (1 % / 99 %) up to 40 %.

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