Abstract
Gas—phase high resolution NMR is a potentially useful new tool for the study of rotational isomerism. The methods of measurement are explained, with the care necessary for sample preparations. The main areas of application at present are a) dynamic NMR study of conformational interconversion processes and b) conformational analysis for populations and energies through coupling constants. For the latter, our recent results on 1,2-disubstituted propanes such as 1,2-dichloropropane, 1,2-di(methoxy- d 3)propane and 1-methoxy-2-propanol are discussed.
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