Gas-phase formation of cationic fullerene/9-aminoanthracene clusters: an indicator for interstellar dust growth

Abstract

ABSTRACT Growth of clusters by adduction of monomers – as the first step in dust particle growth – is an area of much interest in astronomy. We focus on the fullerene/9-aminoanthracene cluster species, to illustrate the competition between the van der Waals bonding growth and the covalent bonding growth model versus the charge transfer model in the large cluster formation process. The experimental results show that fullerene-fragment (C56 and C58)/9-aminoanthracene cluster cations, e.g. [(C14H11N)nC56]+ and [(C14H11N)nC58]+, n = [1,7], are efficiently formed, while C$_{60}^+$ is insensitive to the cluster’s formation. With laser irradiation, all the fullerene/9-aminoanthracene clusters dissociate into 9-aminoanthracene and fullerene cations. The mechanisms for the reactions of fullerene cations and 9-aminoanthracene were investigated by theoretical calculations, under the assumption that the molecular geometries found for the formed complexes correspond to the global energy minima: the absence of C$_{60}^+$ clusters is mainly due to the charge transfer channel’s competition; [(C14H11N)C58]+ has three types of isomers, with van der Waals or covalent bonds, mainly depending on the reaction sites of fullerene cations. Importantly, in the size grown process, for the fullerene/9-aminoanthracene cluster there exists a geometry configuration conversion between the van der Waals and covalent bonding modes. The largest fullerene/9-aminoanthracene clusters, e.g. [(C14H11N)7C58]+ (240 atoms, ∼4 nm in size), are likely in a multishelled geometry, i.e. seven 9-aminoanthracene molecules surrounding fullerene cations in two layers, which can directly build the relationship between molecular clusters and carbonaceous grains. Nitrogen matters! The specific side chains (e.g. –NH2) play an important role in the growth of interstellar dust.