Abstract
Although an important industrial catalyst for producing high density polyethylene, the SiO2-supported organosilyl chromate UCC S-2 catalyst has not been fully investigated compared with the SiO2-supported oxo chromium Phillips catalyst. In this work, gas phase ethylene polymerization by S-2 catalysts (Cat-1, Cat-2, and Cat-3) was carried out in a high-speed stirredautoclave reactor. The effects of temperature, time, and pressure on kinetics, activity, and product properties were studied. All kinetics were typical built-up types with slow decay. Compared to the simple physical mixtures of Cat-1 and Cat-2, Cat-3 showed higher activity and its product had a broader molecular weight distribution, indicating new active species induced during blending of Cat-1 and Cat-2 in n-hexane. The innovation by a simple catalyst technology created a new application to meet market demands.
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