Abstract
The analogy between first-order decomposition of gaseous ions via ion-neutral complexes and solvolytic elimination is explored using an MS/MS technique, chemical ionization-metastable ion kinetic energy spectroscopy (CI-MIKES). Expulsion of propene from M+2 conjugate acid ions in the methane-d 4 CI-MIKES of n-propyl phenyl ethers shows isotopic exchange that is difficult to explain unless complexes containing propene and PhOHD + are formed reversibly
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.