Abstract
The analogy between first-order decomposition of gaseous ions via ion-neutral complexes and solvolytic elimination is explored using an MS/MS technique, chemical ionization-metastable ion kinetic energy spectroscopy (CI-MIKES). Expulsion of propene from M+2 conjugate acid ions in the methane-d 4 CI-MIKES of n-propyl phenyl ethers shows isotopic exchange that is difficult to explain unless complexes containing propene and PhOHD + are formed reversibly
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