Gas–liquid mass transfer in rotating solid foam reactors

Abstract

Three-phase reactor designs based on rotating solid foams for the application in the fine chemical industry are developed. The aim is to use solid foams both as a catalyst support and stirrer in order to mix the gas and liquid phases and create fine gas bubbles. Gas–liquid mass transfer data are presented for different solid foam stirrer configurations and compared to an optimized Rushton stirrer. Solid foam stirrers were developed in a blade and a block design. Both foam reactor designs work at stirring rates below 600 rpm. Using the foam blade design, gas bubbles are mainly created by the turbulence at the gas–liquid interface. Large bubbles are broken up by the foam blades. Using a foam block design, rotation leads to the structurization of the reactor volume into sections strongly differing in gas holdup, flow behavior and bubble size distribution. This results in a gas–liquid mass transfer, which is 50% higher than the Rushton stirrer used as comparison. The foam stirrer designs can be easily used in ordinary three-phase reactors and show a high potential for further optimization of the gas–liquid flow pattern and therefore for further increase of the rate of mass transfer.