Abstract
AbstractThe fatty acids from the seed oils of three Conifer species (one Pinaceae,Pinus pinaster, and two Cupressaceae,Chamaecyparis lawsoniana andBiota orientalis) have been analyzed as their 4,4‐dimethyloxazoline (DMOX) derivatives by gas‐liquid chromatography coupled with mass spectrometry. The structures of six Δ5‐unsaturated polymethylene‐interrupted fatty acids (Δ5‐UPIFA) were established, confirming previous studies in which they were identified by their equivalent chainlengths (ECL) and by comparison with related authentic standards. These acids were:cis‐5,cis‐9 18∶2,cis‐5,cis‐9,cis‐12 18∶3 (P. pinaster),cis‐5,cis‐9,cis‐12,cis‐15 18∶4 (C.lawsoniana),cis‐5,cis‐11 20∶2,cis‐5,cis‐11,cis‐14 20∶3 (all species),cis‐5,cis‐11,cis‐14,cis‐17 20∶4 (B. orientalis) acids. In addition,cis‐9 18∶1,cis‐9,cis‐12 18∶2 (all species) andcis‐9,cis‐12,cis‐15 18∶3 (Cupressaceae) acids, together with their elongation products [cis‐11 20∶1,cis‐11,cis‐14 20∶2 (all species) andcis‐11,cis‐14,cis‐17 20∶3 (B. orientalis) acids] were also identified. In the mass spectra, DMOX derivatives of all Δ5‐UPIFA showed an intense peak atm/z 153, which is a diagnostic ion of fatty acid derivatives with a Δ5‐ethylenic bond. Other double bonds were localized by ion pairs that differed by 12 atomic mass units. The present study fully justifies the use of ECL to identify Δ5‐UPIFA in Conifer seed oils, in which they are ordinary components.
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