Abstract

Abstract Gas-liquid partition chromatography of a number of N-acetyl-n-butyl esters of amino acids has been investigated. Results obtained with a column packed with methyl silicone grease (DC-200, 12,500 est viscosity) were better than those reported for Carbowax 1540 or hydrogenated vegetable oil. Amino acid derivatives were distinctly resolved on methyl silicone grease columns. Preliminary determinations were obtained for synthetic mixtures of the acids. The method should prove a useful adjunct to current techniques for the separation and quantitative measurement of amino acids.

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