Abstract

Methane seepage from the upper continental slopes of Western Svalbard has previously been attributed to gas hydrate dissociation induced by anthropogenic warming of ambient bottom waters. Here we show that sediment cores drilled off Prins Karls Foreland contain freshwater from dissociating hydrates. However, our modeling indicates that the observed pore water freshening began around 8 ka BP when the rate of isostatic uplift outpaced eustatic sea-level rise. The resultant local shallowing and lowering of hydrostatic pressure forced gas hydrate dissociation and dissolved chloride depletions consistent with our geochemical analysis. Hence, we propose that hydrate dissociation was triggered by postglacial isostatic rebound rather than anthropogenic warming. Furthermore, we show that methane fluxes from dissociating hydrates were considerably smaller than present methane seepage rates implying that gas hydrates were not a major source of methane to the oceans, but rather acted as a dynamic seal, regulating methane release from deep geological reservoirs.

Highlights

  • Methane seepage from the upper continental slopes of Western Svalbard has previously been attributed to gas hydrate dissociation induced by anthropogenic warming of ambient bottom waters

  • Observed methane seepage from the upper continental slope of northwestern Svalbard at ~ 400 m water depth has been attributed to gas hydrate dissociation induced by warming of ambient bottom waters and postulated as the onset stage of this future trend[7]

  • We find that seafloor methane seepage subsequently increased because the permeability of sediments was enhanced by the decay of hydrates that previously clogged the pore space, thereby enhancing methane release from underlying geological reservoirs

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Summary

Introduction

Methane seepage from the upper continental slopes of Western Svalbard has previously been attributed to gas hydrate dissociation induced by anthropogenic warming of ambient bottom waters. Vast amounts of methane are bound in gas hydrates that accumulate in seafloor sediments across continental margins These ice-like solids are stable under high pressure/ low temperature conditions but dissociate under ocean warming or relative sea-level lowering. Observed methane seepage from the upper continental slope of northwestern Svalbard at ~ 400 m water depth has been attributed to gas hydrate dissociation induced by warming of ambient bottom waters and postulated as the onset stage of this future trend[7]. We find remnant freshwater from hydrate dissociation that was formed over the last 8000 years when isostatic rebound induced by the deglaciation of the Barents Sea ice sheet outpaced eustatic sea-level rise. We find that seafloor methane seepage subsequently increased because the permeability of sediments was enhanced by the decay of hydrates that previously clogged the pore space, thereby enhancing methane release from underlying geological reservoirs

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