Abstract

Abstract The magneto-optic Cotton-Mouton effect constant C , light refraction index n and density ρ of binary solutions of toluene in carbon tetrachloride, α-picoline and β-picoline in 1,4-dioxane have been measured at different concentrations. The results have been used for the calculation of the molar C M constants of the solutions. By extrapolating the values C M = C M ( f 2 ) for the concentration f 2 → 0, the constant ∞ C 2 M = gas C 2 M of the dipolar component of the solution has been found, which is interpreted as the Cotton-Mouton gas constant. For all solutions, the reduction factors of the dissolved component have been calculated and their linear dependence on the solution concentration has been found.

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