Abstract
Interfacial adsorption is shown to influence the gas chromatographic retention behaviour of hydrocarbons when using glycols as stationary phases. This interfacial effect can be neglected only for lower aromatic hydrocarbons, as demonstrated by the determination of partition and interfacial adsorption coefficients. Activity coefficient at infinite dilution were calculated; they compare favourably with those determined statically when using the method proposed by Martire et al. for the evaluation of exposed areas, whereas the use of experimental values given by Serpinet et al. led to erratic results. Solution and adsorption thermodynamic characteristics of the systems studied are briefly discussed.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
