Abstract
A thermodynamic analysis of the dependence of retention values on the composition of binary stationary phases in gas-liquid chromatography is presented. The existence of extrema (maxima or minima) in the solute retention-binary stationary phase composition plots is shown experimentally. It has been established that the appearance of extrema is due to an interaction between the components of the binary stationary phase. The positions of the extrema relate to the compositions of the molecular compounds being formed.
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