Abstract

An equation is proposed to determine the value of the partial molar enthalpy of solution of the substance under investigation from its retention indices. The values of the enthalpy of solution obtained for benzene, cyclohexane, diethylsulfide, di-n-propylsulfide, dimethyldisulfide, diethyldisulfide, n-propylmercaptan, n-butylmercaptan in apiezon-M and polyethyleneglycol-1000 have been for the first time determined by two methods: through the specific retention volumes and by means of our equation.

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