Garnet–Quartz Inclusion Thermobarometry and Lu–Hf Chronology Detail the Pre-Ultra-High Pressure Metamorphic History of the Grapesvare Nappe, Scandinavian Caledonides

Abstract

ABSTRACT The subduction–exhumation history of the Grapesvare nappe in the northern Seve Nappe Complex (Scandinavian Caledonides) is recorded by late Cambrian/Early Ordovician ultra-high pressure (UHP) and subsequent amphibolite facies metamorphic events. Records of these events obscured earlier metamorphic episodes that are important for understanding the tectonics of the orogen. To extract the pre–UHP metamorphic records, garnet Lu–Hf geochronology, Titanium-in-Quartz thermobarometry, and Quartz-in-Garnet elastic thermobarometry were applied to garnet porphyroblasts in metasedimentary rocks and eclogite. Metasedimentary rocks contain chemically homogeneous garnet (Grt-M1) with shape-matured quartz inclusions. In some rocks, these garnets are overgrown by garnet with bell-shaped Mn-zoning (Grt-M2) containing irregularly-shaped quartz inclusions. This evolution is interpreted as partial dissolution of Grt-M1 and subsequent growth of Grt-M2. Garnet in the eclogite is volumetrically dominated by eclogite-facies garnet (Grt-E1) that envelope remnants of an older, chemically distinct generation (Grt-E0) with highly irregular and diffuse boundaries. Shape-matured quartz inclusions are present within both garnet generations and define a zoning pattern that is not reflective of the chemical zoning. Collectively, these characteristics are interpreted as replacement of Grt-E0 by Grt-E1 via interface-coupled dissolution–reprecipitation, with the latter inheriting the shape-matured quartz inclusions of the former. Pressure–temperature (P–T) conditions extracted from the quartz inclusions in Grt-M1 and Grt-E0/E1 are 1.08 to 1.21 GPa at 645°C to 695°C and 0.94 to 1.03 GPa at 605°C to 640°C, respectively. These conditions are interpreted as cooling of the rocks from a high temperature metamorphic history, altogether preceding subduction of the Grapesvare nappe. The quartz inclusions in Grt-M2 record 1.04 to 1.21 GPa at 620°C to 675°C, interpreted as prograde metamorphic growth of Grt-M2 during subduction at 495.7 ± 3.2 Ma. Subsequent eclogite-facies metamorphism was responsible for the formation of Grt-E1 at the expense of Grt-E0. The collective results indicate a prolonged polymetamorphic history of the Grapesvare nappe prior to UHP metamorphism that has not been recognized previously.