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Abstract
The 1:1 and 1:3 reactions of GaCl 3 with benzotriazole (Hbta) in toluencce-diethyl ether afforded the pseudotetrahedral adduct [GaCl 3(Hbta)] ( 1) and the novel trigonal-bipyramidal species [GaCl 3(Hbta) 2] ( 2), respectively, crystal structures of which have been determined. Some spectroscopic properties of the prepared complexes are also discussed.
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