Abstract

A modified ap ligand, 2-(3,5-dimethoxyanilino)pyridine (HDiMeO ap) and its diruthenium compounds Ru 2(DiMeO ap) 4Cl ( 1), Ru 2(DiMeO ap) 4(C CC CSiMe 3) ( 2) and Ru 2(DiMeO ap) 4(C CC CSiMe 3) 2 ( 3) were prepared and characterized. New compounds Ru 2(MeO ap) 4(C CC CSiMe 3) x ( x = 1, 4; 2, 5; MeO ap is 2-(3-methoxyanilino)pyridinate) were prepared from the previously reported Ru 2(MeO ap) 4Cl. In addition, two related diruthenium compounds containing ferrocenyl acetylide ligand, Ru 2(MeO ap) 4(C CFc) ( 6) and Ru 2( ap) 4(C CC CFc) ( 7), were synthesized. Molecular structures of compounds 1, 2, 6 and 7 were established using single crystal X-ray diffraction study.

Full Text
Paper version not known

Talk to us

Join us for a 30 min session where you can share your feedback and ask us any queries you have

Schedule a call

Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.