Abstract
The use of iodosylbenzene with the iron-bleomycin complex in the olefin epoxidation leads to the questionable role of iron-oxo in this oxygenation reaction (Tetrahedron Letters, 1985, 26, 4699-4702). Oxygenation of olefins is also observed when potassium hydrogen persulfate, KHSO5, is used as oxygen donor and the reported data support a possible role of metal-oxo species in these oxygen transfers mediated by manganese- or iron-bleomycin complexes.
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