Abstract

An earlier theory which took into account intermolecular obstruction in rubber is reconsidered. On the basis of a revised procedure for counting configurations of polymer chains, a new equation of state is obtained relating stress to strain in uniaxial extension. The new relationship has the same from as a function of the strain but differs in its dependence on f, the fraction of the rubber volume occupied by the polymer chains. When applied to experiments, it leads to higher values of f. In addition, results presented previously only for uniaxial extension are generalized for arbitrary strains.

Full Text
Paper version not known

Talk to us

Join us for a 30 min session where you can share your feedback and ask us any queries you have

Schedule a call

Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.