Fundamental Insight into Zr Modification of Li- and Mn-Rich Cathodes: Combined Transmission Electron Microscopy and Electrochemical Impedance Spectroscopy Study

Abstract

While zirconium-based coatings are known to improve the cycling stability of a number of lithium ion battery cathodes, the microstructural origin of this enhancement remains uncertain. Here we combine advanced transmission electron microscopy (high-resolution transmission electron microscopy, high-angle annular dark field, electron energy loss spectroscopy, and energy-dispersive X-ray spectroscopy) with electrochemical impedance analysis to provide new insight into the dramatic role of Zr surface modification on the electrochemical performance of Li- and Mn-rich (LMR) cathodes (Li[Li0.2Ni0.13Co0.13Mn0.54]O2). It is demonstrated that a Zr-based rock-salt structure layer with a thickness of 1–2 nm is formed on the surface of the LMR. This layer is effective in suppressing the deleterious phase transformation of LMR from initial layered composite combining Li2MO3 and LiMO2 to the disordered rock-salt phase, leading to an enhanced long-term cycling performance and rate capability. Electrochemical impedance sp...