Abstract
Funktionell substituierte Vinylcarbanionen, 29. Reaktion einer β-lithiierten Acrylsaure mit Oxetanen als Electrophil β-Lithiiertes β-(Ethylthio)acrylat 1A reagiert mit den Oxetanen 2 bzw. (±)-5 in Anwesenheit von Bortrifluorid-Ether zu den entsprechenden γ-hydroxypropyl-substituierten Derivaten 3 bzw. 6. Von den 2-Alkyl/phenyl-3-ethoxy-oxetanen (±)-5 reagieren die erythro-Derivate deutlich rascher als die threo-Derivate.
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