Functionalized phosphine-phosphinimines as heteroatomic ligands. Synthesis, characterization, and representative x-ray structures of the phosphine-phosphinimines Ph2PCH2PPh2:NAr [Ar = 5-F,2,4-(NO2)2C6H2, 4-(CN)C6F4] and structure of the rhodium(I) complex Cl(CO)RhP(Ph)2CH2PPh2:NC6F4-4-CN

Kattesh V Katti,Ronald G Cavell,A Alan Pinkerton,B D Santarsiero

doi:10.1021/ic00078a006

Functionalized phosphine-phosphinimines as heteroatomic ligands. Synthesis, characterization, and representative x-ray structures of the phosphine-phosphinimines Ph2PCH2PPh2:NAr [Ar = 5-F,2,4-(NO2)2C6H2, 4-(CN)C6F4] and structure of the rhodium(I) complex Cl(CO)RhP(Ph)2CH2PPh2:NC6F4-4-CN

Kattesh V Katti, Ronald G Cavell + Show 2 more

https://doi.org/10.1021/ic00078a006

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Journal: Inorganic chemistry	Publication Date: Dec 1, 1993
Citations: 50

Affiliation: University of Alberta, University of Toledo

#Heteroatomic Ligands #Reaction Of Me + Show 6 more

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Abstract

Reaction of the (trimethylsilyl)phosphinimine-phosphine Me 3 SiN=PPh 2 CH 2 PPh 2 with nitro-fluoro aromatics and aromatic fluoro nitriles (containing at least one activated fluorine on the position which becomes, as the point of attachment to the imine nitrogen, position 1 of the ring) in refluxing toluene gave the phosphinimine-phosphines

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