Functionalized MoO3 Nanosheets for High-Efficiency RhB Removal.

Abstract

2D nanostructured materials have been applied for water purification in the past decades due to their excellent separation and adsorption performance. However, the functional 2D nanostructured molybdenum trioxide (MoO3)has rarely been reported for the removal of dyes. Here, functionalized MoO3 (F-MoO3) nanosheets are successfully fabricated with a high specific surface area (106cc g-1) by a one-step mechanochemical exfoliation method as a highly effective adsorbent for removing dyes from water. According to the Raman, X-ray photoelectron spectroscopy, Fourier transform infrared (FTIR), and selected area electron diffraction analysis, functional groups (hdroxyl groups, amide groups, amine groups and amino groups) are identified in the as-prepared F-MoO3 nanosheets. The attached functional groups not only facilitate the dispersal ability of F-MoO3 nanosheets but also enhance the adsorption capacities. Thus, the performance (up to 556mgg-1 when the initial concentration of Rhodamine B solution is 100mg L-1) of as-prepared F-MoO3 nanosheets is almost two times higher than other reported MoO3 materials. Furthermore, the FTIR spectra, isotherm, and several factors (e.g., adsorbent dosage and adsorbate dosage) are also systematically investigated to explore the adsorption mechanism. Therefore, this work demonstrates that the F-MoO3 nanosheets are a promising candidate for wastewater treatment.