Abstract

This study presents a sensitive colorimetric probe for sensing Co2+ ions based on surface amine-modified iron oxide–silica core–shell nanoparticles (APTES–Fe@SiO2 NPs) and the appearance of an additional plasmonic peak in the UV–vis spectra due to NP aggregation. This colorimetric strategy based on the component dependence of core–shell NPs offered a highly sensitive and selective detection method for Co2+ ions. This cost-effective colorimetric probe afforded rapid, naked-eye detection of trace Co2+ ions at concentrations as low as 0.08mM. The amine moiety of APTES–Fe@SiO2 NPs readily formed the metal–amine configuration complex (λ980 peak) and induced the formation of Co NPs by self-seed generation (λ520, λ590, and λ630 peaks). Preliminary study data supported the promising practical applicability of the current method for the colorimetric detection of Co2+ ions in aqueous phase.

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