Abstract

Abstract The recent increase in the use of graphene and its derivatives is due to their exceptional physicochemical, electrical, mechanical, and thermal properties as the industrial materials developed by involving graphene structures can fulfill future needs. In that view, the potential use of these graphene-containing nanomaterials in electronics applications has encouraged in-depth exploration of the electronic, conducting, and other functional properties. The protecting undifferentiated form of graphene has similarly been proposed for various applications, for example, as supercapacitors, photovoltaic and transparent conductors, touch screen points, optical limiters, optical frequency converters, and terahertz devices. The hybrid composite nanomaterials that undergo stimulus-induced optical and electrical changes are important for many new technologies based on switchable devices. As a two-dimensional smart electronic material, graphene has received widespread attention, and with that view, we aim to cover the various types of graphene oxide (GO)-based composites, linking their optical and electrical properties with their structural and morphological ones. We believe that the topics covered in this review can shed light on the development of high-yield GO-containing electronic materials, which can be fabricated as the field moves forward and makes more significant advances in smart optoelectronic devices.

Highlights

  • Graphene is exciting as the gateway to a new era in materials science and technology research because of its ability to convert itself into many different forms with a change of structure and dimensionality

  • We have focused on the recent research including the synthesis and applications of graphene-based nanocomposites

  • It doesn’t matter which mechanism is used for photoluminescence of graphene-derived QDs (GQDs), but it has the same characteristics; the excitation wavelength is responsible for the changes in emission spectrum wavelength

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Summary

Introduction

Graphene is exciting as the gateway to a new era in materials science and technology research because of its ability to convert itself into many different forms with a change of structure and dimensionality. The graphene with its 2D carbon sheet maintains several other magical properties such as the thickness similar to that of a single-atom, large theoretical surface area, high conductivity at room temperature, and wider electrochemical window [3] In addition to those magical properties, the graphene nanosheets (NSs) can serve as an excellent host material for the growth of high-performance nanomaterials with enhanced electrochemical characteristics [4,5,6,7]. The exceptional properties of graphene are derived from the 2p orbitals of π-state bands; as a result, the graphene inherits various characteristics, such as being optically transparent and having better surface area, excellent thermal conductivity, and mechanical properties [32] These characteristics furnish graphene with a significant dominance over similar materials used in diverse industrial applications. Though the special focus of this article is on graphene and functionalized graphene-based materials for optical applications, it provides an overview of graphene synthesis (bottom-up and top-down approaches) and its characteristics, since graphene is the main roll material of the current review article

Properties of graphene
Optical properties
Luminescence
Synthesis approaches of graphene
Top-down approach
Bottom-up approach
Functionalization of graphene
Functionalization with molecules
Functionalization with nanoscale objects
Functionalization with polymers
Photonic and optoelectronicrelated applications
Photovoltaic cells
Electrochemical sensors
Optical and fiber-based biosensor probes
Optical limiters
Optical frequency converters
Transparent conductors
Terahertz devices
Photodetectors
Findings
Conclusion and future directions
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