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Abstract
Abstract The dihydropyridine-induced reduction of alkoxycarbene complexes of chromium has been generalized to differently substituted dihydropyridines, e.g. N -benzyl dihydropyridine and N -methyl- N’N’ -diethyldihydronicotinamide. In all the cases examined, alkoxyalkynyl carbene complexes lead, upon cascade insertions, to butenolides, the diastereomeric excesses being dependent on the structure of the dihydropyridines.
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Schedule a callMore From: Comptes Rendus de l'Académie des Sciences - Series IIC - Chemistry
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