Functionalization of UiO-66-NH2 with rhodanine via amidation: Towarding a robust adsorbent with dual coordination sites for selective capture of Ag(I) from wastewater

Abstract

Selective capture and maximum recovery of Ag(I) from wastewater is of great significance for a sustainable future. In this work, novel rhodanine (Rd)-functionalized UiO-66 adsorbents (i.e., UiO-66-Rd and UiO-66-NH2-Rd) were designed and synthesized. Different from previously reported UiO-66 derivatives with single metal coordination sites, the as-synthesized UiO-66-Rd and UiO-66-NH2-Rd have dual coordination sites, resulting in higher capacity and outstanding selectivity. The maximum capacities of UiO-66-Rd and UiO-66-NH2-Rd are 112 and 163 mg·g−1, nearly 5.6 and 8.2 times higher than that of UiO-66, respectively. Impressively, the maximum selectivity coefficient of UiO-66-NH2-Rd is approximately 1795 and 1173 folds higher than that of UiO-66 and UiO-66-NH2. The experimental characterizations and theoretical calculations indicate that the Rd-induced enhancement in the adsorptivity and selectivity are mainly attributed to the dual coordination sites (i.e., CS and CS bonds), which collectively coordinate with Ag(I) in the form of Ag mono-coordinated with S. Compared with the UiO-66-Rd, UiO-66-NH2-Rd possesses excellent recyclability and durability due to the vital role of amide bonds generated from NH2 group in the functionalization of UiO-66 with Rd. Furthermore, UiO-66-NH2-Rd can almost completely remove Ag(I) from the actual wastewater with complex matrix, satisfying the national integrated wastewater discharge standard and industrial wastewater emission standard, highlighting a great potential of practical application.