Abstract
AbstractThe chloroiodomethyl chain ends of poly(vinyl chloride) (PVC) obtained by the single‐electron‐transfer/degenerative‐chain‐transfer mediated living radical polymerization of vinyl chloride initiated with iodoform were quantitatively functionalized by the reaction with 2‐allyloxyethanol (CH2CHCH2OCH2CH2OH). This reaction was performed in dimethyl sulfoxide at 70 °C and was catalyzed by sodium dithionite/sodium bicarbonate. The resulting product is the first example of telechelic PVC [α,ω‐di(hydroxy)PVC]. A possible mechanism for this reaction was suggested. © 2005 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 43: 1255–1260, 2005
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