Abstract
AbstractThe functionalisation of semiconductor (particularly silicon) surfaces have been an active area of research in the past two decades. The surface modification of silicon has opened up new potential applications of this material. In the present work the macroporous silicon surfaces have been effectively functionalised using tetrazine derivatives. The work involved: i) preparation of cyclopentadienyl‐modified silicon surfaces; (ii) modification of the surface by cycloaddition of tetrazines with dimethyl pyrazolyl functionality; (iii) characteristion of functionalised silicon samples by electron microscopy, FT‐IR, Raman, and photoluminescence spectroscopy. The obtained composite materials might have potential application as sensors and components for molecular electronics. (© 2009 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)
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