Functionalisation of Carbon Catalyst Support By Plasma Treatment for PEMFC Cathode

Abstract

Proton exchange membrane fuel cell (PEMFC) is one promising electric device to replace the combustion engine using fossil fuel especially for heavy-duty transport. One of the main issue for the widespread of this technology on the European roads is the cost and degradation of their components over time. The sluggish reduction of dioxygen at the cathode require high amount of noble metal (i.e. platinum). Under PEMFC operating conditions, carbon as catalyst support is unstable.This study presents a new approach to improve the stability of the cathode components (catalyst, carbon support and ionomer) thanks to the enhancement of the interaction between the three entities and to reduce carbon corrosion. Plasma treatment were performed on different carbon black sources (different surface area and porosity) to functionalize their surface by nitrogen function using different gas. The modified carbons were characterized by TEM, XPS, Raman spectroscopy, calorimetry, elemental analysis. The plasma treatments were reproducible and allow controlling the degree of functionalisation. The nitrogen doped carbons were catalysed by platinum nanoparticles. A better dispersion of the nanoparticles was observed by TEM showing the interest of the plasma treatment. Cyclic voltammetry were performed and a better catalytic activity toward the electrochemical reduction of O2 was observed.[1] Isothermal titration calorimetry experiments were carried out and show an improved interaction between the nitrogen functionalized carbon and the ionomer.[1] A. Parnière, P.-Y. Blanchard, S. Cavaliere, N. Donzel, B. Prelot, J. Rozière, D.J. Jones, Nitrogen Plasma Modified Carbons for PEMFC with Increased Interaction with Catalyst and Ionomer, J. Electrochem. Soc. 169 (2022) 044502. Figure 1