Abstract

Due to its ability to degrade nitrogen oxides under ultraviolet, titanium dioxide has been applied in asphalt concrete to degrade automobile exhaust in recent years. To highlight the protection of road traffic environmental quality and mitigate automobile exhaust on human health, this study proposes combining titanium dioxide and active carbon into Sand-fog seal to form a pavement coating material with a photocatalytic function. It uses active carbon to reinforce the material’s function, and the coupling agent for modification makes it well dispersed in the Sand-fog seal. The indoor experiments were carried out at 30 °C and relative humidity of 30%. It tested the composite material’s degradation efficiency on nitrogen dioxide in relation to component proportions, coupling agents, and dosages. The study concluded that the optimal photocatalytic efficiency could be achieved when the ratio of active carbon to titanium dioxide is 0.6. After being modified by the titanate coupling agent and through Scanning Electron Microscope tests, it can be seen that materials can be well dispersed into the Sand-fog seal. When the composite material accounts for 10% of the fog seal, it can achieve the optimal photocatalytic efficiency of about 23.9%. The British pendulum tests show it has good skid resistance performance. Half a kilometer of concrete roadway was sprayed with the material coating in Tianjin, China. The photocatalytic experimental road degrades nitrogen oxides better than the original road. The method is feasible for practical implementation.

Highlights

  • In urban road traffic, nitrogen oxides (NOx ) emissions from vehicle exhaust coexist with people in a specific area [1,2]

  • The results show evidence of a photocatalytic reaction occurring in the field, and the degradation rate of nitrogen oxide could reach

  • This study suggests the optimal ratio of Sand-fog seal material with photocatalytic function

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Summary

Introduction

Nitrogen oxides (NOx ) emissions from vehicle exhaust coexist with people in a specific area [1,2]. They are inhaled by the human body and affect the physical and mental health of people. Mitigating exhaust emissions has become the focus of protecting road traffic environmental quality [3,4]. Studies have found that titanium dioxide (TiO2 ) as a photocatalyst can significantly increase pollutants’ degradation efficiency. Titanium dioxide has good chemical stability compared with semiconductor photocatalyst. The principle of photocatalytic decomposition of automobile exhaust is illustrated in the following Formulas (1)–(3): CO + O2

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