Abstract
An excellent asymmetric induction (enantiomeric excess >90%) is achieved in the Ī±āalkylation of esters of carboxylic acids and the alcohols (1) or (2) (see previous contribution). A drastic solvent effect (THF or THFāHMPT 4:1) enables each of both enantiomers of a compound to be synthesized in high optical purity.
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