Abstract
Mellophanic dianhydride which is aromatic tetracarboxylic dianhydride monomer for synthesis of polyimide, were derived from maleic anhydride and 2,5-dimethylfuran as the bio-derived monomers with the new approach. The obtained mellophanic dianhydride is used to synthesize the fully bio-based poly(amic acid) using 4-aminocinnamic acid dimer as the bio-based aromatic diamine monomer. For controlling the solubility of polyimide, thermal or chemical imidizations are carried out by using stepwise heating method or acetic anhydride/pyridine treatment, respectively. Thermally imidized polyimides show low solubility for organic solvent, however, chemically-imidized polyimide show good solubility for N-methyl-2-pylloridione, dimethylsulfoxide, and N,N-dimethylformamide. In addition, all the obtained polymers show high heat resistance properties, 10 % decomposed temperature (T d10), of poly(amic acid) is 331 °C, while T d10 of polyimides are 389 °C regardless of imidization processes. Thus, fully bio-based polyimides having high thermostability is developed for the first time.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a call
