Fully aminated p‐polyaramid effectively strengthen and toughen Bisphenol A epoxy resin and its warp‐knitted carbon fiber composites

Abstract

AbstractStemming from the cost‐effectiveness and broad applicability, many modification researches on Bisphenol A epoxy resin (DGEBA) and its carbon fiber composites have been done extensively. Here, following the concept of molecular composite, we prepared fully aminated p‐polyaramid with reactive amino side groups by polycondensation and reduction reaction, aiming to construct a molecular distribution of the reinforcement within the resin matrix and achieve a satisfactory enhancement effect. Among them, after adding 1 wt% fully aminated p‐polyaramid, Young's modulus and tensile toughness of the DGEBA epoxy resin (EP) increased significantly to 2.34 ± 0.03 GPa (+68.3%) and 4402 ± 213 kJ/m3 (+30.5%), the flexural modulus and toughness reached 4.14 ± 0.04 GPa (+42.8%) and 0.44 ± 0.01 J (+83.3%). Moreover, the Tg of EP was only decreased by 2.7°C. In addition, their warp‐knitted bidirectional carbon fiber composites also have enhancements in both flexural properties and interlaminar shear strength (all improved by more than 20%). What is noticeable is that the preparation and blending of fully aminated p‐polyaramid are simpler and more effective than most other micro‐ or nanofillers, and the dispersion is more uniform. Thus, it can act as a highly effective reinforcement and strengthen the properties of DGEBA and its carbon fiber composite materials significantly.Highlights Fully aminated p‐polyaramid is uniformly dispersed in EP by chemical bonds. DGEBA is strengthened and toughened without a significant decrease in Tg. The tensile and flexural modulus of EP is increased by 68.3% and 42.8%. Fully aminated p‐polyaramid can reinforce warp‐knitted carbon fiber composite.