Abstract

A spectral method is developed to determine the content of fullerene in polymers formed in its presence during the free-radical polymerization and copolymerization of methyl methacrylate, allyl methacrylate, allyl chloride, and styrene. The method is based on measurement of absorption coefficients for the ππ*-excited transition of fullerene cores at 330 nm that is due to their insertion into a polymer chain and the related distortion of the closed polyene system of carbon-carbon bonds.

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