Fuel-Driven Dissipative Self-Assembly of a Supra-Amphiphile in Batch Reactor.

Abstract

Dissipative self-assembly is an intriguing but challenging research topic in chemistry, materials science, physics, and biology because most functional self-assembly in nature, such as the organization and operation of cells, is actually an out-of-equilibrium system driven by energy dissipation. In this article, we successfully fabricated an I2-responsive supra-amphiphile by a PEGylated poly(amino acid) and realize its dissipative self-assembly in batch reactor by coupling it with the redox reaction between NaIO3 and thiourea, in which I2 is an intermediate product. The formation and dissipative self-assembly of the supra-amphiphile can be repeatedly initiated by adding the mixture of NaIO3 and thiourea, which herein acts as "chemical fuel", while the lifetime of the transient nanostructures formed by the dissipative self-assembly is easily tuned by altering thiourea concentration in the "chemical fuel". Furthermore, as an application demo, the dissipative self-assembly of the supra-amphiphile is examined to control dispersion of multiwalled carbon nanotubes in water, exhibiting a good performance of organic pollutant removal.