Abstract
Infrared absorption by CO and CO2 adsorbed on NaCl (film) and NaCl(100) single crystal surfaces has been measured under ultrahigh vacuum conditions as a function of temperature and pressure, using grating and FTIR transmission-absorption spectroscopy. The absorption line of a monolayer of CO on NaCl(100) due to the stretching vibration is extremely narrow (<2 cm−1) and onlyp-polarized light is absorbed at oblique incidence. Resonant desorption in CO-NaCl (film) has been detected. Thev3 absorption of a monolayer of CO2 on NaCl(100) appears as a doublet.
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