FTIR study of NO, C 3H 6 and O 2 adsorption and interaction on gold modified MCM-41 materials

Abstract

This paper is devoted to the detailed FTIR study of the adsorption, co-adsorption, and interaction of all the reagents used in NO HC-SCR process addressed to lean-burn engines with the surface of new gold catalysts based on ordered mesoporous materials. Gold was introduced into silicate and niobiosilicate matrices by the impregnation (Au/MCM-41 and Au/NbMCM-41, respectively) and via co-precipitation with siliceous and niobium sources (AuNbMCM-41). The in situ FTIR study allowed the estimation of the possible chemisorption of the reagents and their interaction towards intermediates, depending on the chemical composition of the catalyst and the way of gold introduction. It has been found that propene is chemisorbed, but not, NO, on gold species at room temperature. Chemisorbed C 3H 6 interacts with NO only in the presence of oxygen excess. Oxygen oxidizes NO to NO 2, the latter interacts with chemisorbed propene towards carboxylates (∼1570 cm −1) and NO 2 is reduced to N 2O. At higher temperatures carboxylates interact with gaseous NO to carbonate, N 2O, CO and CO 2. The presence of niobium in the NbMCM-41 matrix enhances the oxidative properties of the catalysts and as a consequence the interaction between intermediates in NO reduction with propene in the oxygen excess. The co-precipitated AuNbMCM-41 exhibits higher NOx storage properties than the impregnated one.