Abstract
Raman and Infrared spectroscopies have been employed to investigate the 25Bi2O3-(75-x)B2O3-xBaO glasses in order to obtain information about the competitive role of Bi2O3 and B2O3 in the formation of glass network. FTIR and Raman spectra show that these glasses are made up of [BO3], [BO4], [BiO3] pyramidal and [BiO6] octahedral units.
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