Froth Treatment in Athabasca Oil Sands Bitumen Recovery Process: A Review

Abstract

Bitumen froth treatment is an integrated process step in the Athabasca oil sands bitumen recovery operations. Its objective is to separate mineral solids and water from the bitumen froth. The bitumen froth is diluted with naphthenic or paraffinic solvents to lower its viscosity to facilitate the separation; therefore, bitumen froth treatment is the removal of inorganics (mineral particles and water droplets) from a bitumen organic solvent solution. The micrometer sized mineral particles (mainly clays) and water-in-oil emulsion droplets are the most difficult to remove from the bitumen froth. Research has been carried out that has led to an understanding of the formation, stabilization and properties of the water-in-oil emulsions in the bitumen organic solvent solution. It is known that the water-in-oil emulsions are formed by water entrained into the bitumen froth during the water-based extraction process and stabilized by natural surfactants in bitumen (especially asphaltene) and fine mineral particles. ...