Abstract
Direct fluoroalkoxylation reactions of (hetero)arenes, carbon-carbon multiple bonds, and substitution reactions at Csp3 carbon centers by CF3O, CHF2O, and (CF3)2CFO groups are discussed in the Review (DOI: 10.1002/chem.202201776) by Postigo, Bonesi, and Barata-Vallejo with an emphasis on thermal radical, electron transfer, photocatalytic, electrochemical and redox-neutral radical methods.
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