Abstract
An efficient distal C(sp3)−H azidation of both ketoxime esters and N-acyloxy imidates for the synthesis of γ-azido ketones and β-azido alcohols is reported in the Full Paper by J. Zhu, et al. on page 9477 ff. The artwork represents two essential processes of the proposed mechanism: the 1,5-hydrogen atom transfer of an imine/imidate radical through a chair-like transition state, and the iron-mediated redox azido transfer to the translocated carbon radical.
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