Abstract

The use of allenes and 1,3-dienes as chiral allylmetal pronucleophiles in intermolecular catalytic enantioselective reductive additions to aldehydes, ketones, imines, carbon dioxide and other C=X electrophiles is exhaustively catalogued in this Minireview by M. J. Krische and colleagues, together with redox-neutral hydrogen auto-transfer processes. For more details, see the Minireview by Michael J. Krische et al. on page 13107 ff.

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