Abstract
Zirconium-based metal-organic framework materials (Zr−MOFs) have more practical usage over most conventional benchmark porous materials and even many other MOFs due to the excellent structural stability, rich coordination forms, and various active sites. However, their mass-production and application are restricted by the high-cost raw materials, complex synthesis procedures, harsh reaction conditions, and unexpected environmental impact, and considerable green chemistry efforts have been applied breaking through the limitations, and significant progress has been made in the sustainable synthesis of Zr−MOFs over the past decade. For more information, see the Review by J. Fu and Y. Wu on page 9967.
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